Dr Eva Krupp

Dr Eva Krupp The University of Aberdeen School of Natural & Computing Sciences Dr Eva Krupp Senior Lecturer work +44 (0)1224 272901

Senior Lecturer

Dr Eva Krupp

Personal Details

Telephone: +44 (0)1224 272901
Email: e.krupp@abdn.ac.uk
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Marine Biodiscovery Centre 


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Research Interests

Dr. Eva Krupp is a lecturer in analytical chemistry, whose expertise is the biogeochemical cycle of anthropogenic and natural pollutants. Her particular field of analytical chemistry is trace element speciation, a discipline which enables the determination of the molecular form of elements such as metals, metalloids and heteroelements in trace amounts in biological and environmental samples. The molecules of interest can be of low molecular mass range and purely of inorganic nature such Cr(III) / Cr(VI), or organometallic compounds such as methylmercury, arsenosugars, tributyltin. Also high molecular mass species such as selenoproteins or metalloproteins, or mercury and arsenic peptide complexes belong to this group.

Dr. Krupp's work focuses on the development of new analytical methods, involving the use of stable enriched isotopes both for the improvement of the analytical process or the use of isotopic fingerprints of elements and element species.

Her recent research is focused on the speciation of mercury biomolecules in biota, for example to determine mercury uptake and biotransformation in plants. Lately, she identified for the first time mercury-biomolecule interactions in rice (Oryza sativa), which may be a key factor to explain mercury bioaccumulation patterns in environment and biota.

Other fields of interest are the biovolatilisation of metals, e.g. from paddy fields or in landfill sites, and she also works in close relation with the oil and gas industry on the determination of trace pollutants in natural gas and gas products.


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Publications

Contributions to Journals

Articles

  • Qin, Z., Raab, A., Krupp, EM., Deng, H. & Feldmann, J. (in press). 'Mining complex bacteria media for all fluorinated compounds made possible by using HPLC Coupled Parallel to Fluorine-Specific and Molecular Specific Detection'. Journal of Analytical Atomic Spectrometry, pp. 877-882.
    [Online] DOI: 10.1039/C3JA50086A
  • Freitag, S., Krupp, EM., Raab, A. & Feldmann, J. (2013). 'Impact of a snail pellet on the phytoavailability of different metals to cucumber plants (Cucumis sativus L.)'. Environmental Sciences: Processes and Impacts, vol 15, no. 2, pp. 463-469.
    [Online] DOI: 10.1039/c2em30806a
  • Siebold, M., Leidich, P., Bertini, M., Deflorio, G., Feldmann, J., Krupp, EM., Halmschlager, E. & Woodward, S. (2012). 'Application of elemental bioimaging using laser ablation ICP-MS in forest pathology: distribution of elements in the bark of Picea sitchensis following wounding'. Analytical and Bioanalytical Chemistry, vol 402, no. 10, pp. 3323-3331.
    [Online] DOI: 10.1007/s00216-011-5657-0
  • Petursdottir, AH., Gunnlaudsdottir, H., Jorundsdottir, H., Raab, A., Krupp, EM. & Feldmann, J. (2012). 'Determination of inorganic arsenic in seafood: Emphasizing the need for certified reference materials'. Pure and Applied Chemistry, vol 84, no. 2, pp. 191-202.
    [Online] DOI: 10.1351/PAC-CON-11-10-03
  • Qin, Z., McNee, D., Gleisner, H., Raab, A., Kyeremeh, K., Jaspars, M., Krupp, E., Deng, H. & Feldmann, J. (2012). 'Fluorine Speciation Analysis Using Reverse Phase Liquid Chromatography Coupled Off-Line to Continuum Source Molecular Absorption Spectrometry (CS-MAS): Identification and Quantification of Novel Fluorinated Organic Compounds in Environmental and Biological Samples'. Analytical Chemistry, vol 84, no. 14, pp. 6213-6219.
    [Online] DOI: 10.1021/ac301201y
  • Petursdottir, AH., Gunnlaugsdottir, H., Joerundsdottir, H., Mestrot, A., Krupp, EM. & Feldmann, J. (2012). 'HPLC-HG-ICP-MS: a sensitive and selective method for inorganic arsenic in seafood'. Analytical and Bioanalytical Chemistry, vol 404, no. 8, pp. 2185-2191.
    [Online] DOI: 10.1007/s00216-012-6347-2
  • Mestrot, A., Feldmann, J., Krupp, EM., Hossain, MS., Roman-Ross, G. & Meharg, AA. (2011). 'Field Fluxes and Speciation of Arsines Emanating from Soils'. Environmental Science & Technology, vol 45, no. 5, pp. 1798-1804.
    [Online] DOI: 10.1021/es103463d
  • Krupp, EM., Merle, JK., Haas, K., Foote, G., Maubec, N. & Feldmann, J. (2011). 'Volatilization of Organotin Species from Municipal Waste Deposits: Novel Species Identification and Modeling of Atmospheric Stability'. Environmental Science & Technology, vol 45, no. 3, pp. 943-950.
    [Online] DOI: 10.1021/es102512u
  • Cui, L., Newcombe, C., Urgast, DS., Raab, A., Krupp, EM. & Feldmann, J. (2011). 'Assessing the toxicity of arsenic-bearing sulfide minerals with the bio-indicator Corophium volutator'. Environmental Chemistry, vol 8, no. 1, pp. 52-61.
    [Online] DOI: 10.1071/EN10044
  • Mestrot, A., Merle, JK., Broglia, A., Feldmann, J. & Krupp, EM. (2011). 'Atmospheric Stability of Arsine and Methylarsines'. Environmental Science & Technology, vol 45, no. 9, pp. 4010-4015.
    [Online] DOI: 10.1021/es2004649
  • Amayo, KO., Petursdottir, A., Newcombe, C., Gunnlaugsdottir, H., Raab, A., Krupp, EM. & Feldmann, J. (2011). 'Identification and Quantification of Arsenolipids Using Reversed-Phase HPLC Coupled Simultaneously to High-Resolution ICPMS and High-Resolution Electrospray MS without Species-Specific Standards'. Analytical Chemistry, vol 83, no. 9, pp. 3589-3595.
    [Online] DOI: 10.1021/ac2005873
  • Berzas Nevado, JJ., Rodriguez Martin-Doimeadios, RC., Krupp, EM., Guzman Bernardo, FJ., Rodriguez Farinas, N., Jimenez Moreno, M., Wallace, D. & Patino Roper, MJ. (2011). 'Comparison of gas chromatographic hyphenated techniques for mercury speciation analysis'. Journal of Chromatography A, vol 1218, no. 28, pp. 4545-4551.
    [Online] DOI: 10.1016/j.chroma.2011.05.036
  • Bertini, M., Shortland, A., Milek, K. & Krupp, EM. (2011). 'Investigation of Iron Age north-eastern Scottish glass beads using element analysis with LA-ICP-MS'. Journal of Archaeological Science, vol 38, no. 10, pp. 2750-2766.
    [Online] DOI: 10.1016/j.jas.2011.06.019
  • Antes, FG., Krupp, E., Flores, EMM., Dressler, VL. & Feldmann, J. (2011). 'Speciation and Degradation of Triphenyltin in Typical Paddy Fields and Its Uptake into Rice Plants'. Environmental Science & Technology, vol 45, no. 24, pp. 10524-10530.
    [Online] DOI: 10.1021/es202832g
  • Jakob, R., Roth, A., Haas, K., Krupp, EM., Raab, A., Smichowski, P., Gomez, D. & Feldmann, J. (2010). 'Atmospheric stability of arsines and the determination of their oxidative products in atmospheric aerosols (PM10): evidence of the widespread phenomena of biovolatilization of arsenic'. Journal of Environmental Monitoring, vol 12, no. 2, pp. 409-416.
    [Online] DOI: 10.1039/b915867g
  • Deitrich, CL., Braukmann, S., Raab, A., Munro, C., Pioselli, B., Krupp, EM., Thomas-Oates, JE. & Feldmann, J. (2010). 'Absolute quantification of superoxide dismutase (SOD) using species-specific isotope dilution analysis'. Analytical and Bioanalytical Chemistry, vol 397, no. 8, pp. 3515-3524.
    [Online] DOI: 10.1007/s00216-010-3680-1
  • Mestrot, A., Uroic, MK., Plantevin, T., Islam, MA., Krupp, EM., Feldmann, J. & Meharg, AA. (2009). 'Quantitative and Qualitative Trapping of Arsines Deployed to Assess Loss of Volatile Arsenic from Paddy Soil'. Environmental Science & Technology, vol 43, no. 21, pp. 8270-8275.
    [Online] DOI: 10.1021/es9018755
  • Krupp, EM., Mestrot, A., Wielgus, J., Meharg, AA. & Feldmann, J. (2009). 'The molecular form of mercury in biota: identification of novel mercury peptide complexes in plants'. Chemical Communications, vol 28, pp. 4257-4259.
    [Online] DOI: 10.1039/b823121d
  • Uroic, MK., Krupp, EM., Johnson, C. & Feldmann, J. (2009). 'Chemotrapping-atomic fluorescence spectrometric method as a field method for volatile arsenic in natural gas'. Journal of Environmental Monitoring, vol 11, no. 12, pp. 2222-2230.
    [Online] DOI: 10.1039/b913322d
  • Bluemlein, K., Krupp, EM. & Feldmann, J. (2009). 'Advantages and limitations of a desolvation system coupled online to HPLC-ICPqMS/ES-MS for the quantitative determination of sulfur and arsenic in arseno-peptide complexes'. Journal of Analytical Atomic Spectrometry, vol 24, no. 1, pp. 108-113.
    [Online] DOI: 10.1039/b811600h
  • Mighall, TM., Timberlake, S., Foster, IDL., Krupp, EM. & Singh, S. (2009). 'Ancient copper and lead pollution records from a raised bog complex in Central Wales, UK'. Journal of Archaeological Science, vol 36, no. 7, pp. 1504-1515.
    [Online] DOI: 10.1016/j.jas.2009.03.005
  • Krupp, EM., Milne, BF., Mestrot, A., Meharg, AA. & Feldmann, J. (2008). 'Investigation into mercury bound to biothiols: structural identification using ESI-ion-trap MS and introduction of a method for their HPLC separation with simultaneous detection by ICP-MS and ESI-MS'. Analytical and Bioanalytical Chemistry, vol 390, no. 7, pp. 1753-1764.
    [Online] DOI: 10.1007/S00216-008-1927-X
  • Krupp, EM. (2008). 'Coupling techniques with ICP-MS'. Nachrichten aus der Chemie, vol 56, no. 5, pp. 555-559.
    [Online] DOI: 10.1002/nadc.200853351
  • Krupp, EM., Johnson, C., Rechsteiner, C., Moir, M., Leong, D. & Feldmann, J. (2007). 'Investigation into the determination of trimethylarsine in natural gas and its partitioning into gas and condensate phases using (cryotrapping)/gas chromatography coupled to inductively coupled plasma mass spectrometry and liquid/solid sorption techniques'. Spectrochimica Acta. Part B: Atomic Spectroscopy, vol 62, no. 9, pp. 970-977.
    [Online] DOI: 10.1016/j.sab.2007.07.009
  • Davis, WC., Christopher, SJ., Pugh, RS., Donard, OFX., Krupp, EA., Point, D., Horvat, M., Gibicar, D., Kljakovic-Gaspic, Z., Porter, BJ. & Schantz, MM. (2007). 'Certification of methylmercury content in two fresh-frozen reference materials: SRM 1947 Lake Michigan fish tissue and SRM 1974b organics in mussel tissue (Mytilus edulis)'. ANALYTICAL AND BIOANALYTICAL CHEMISTRY, vol 387, no. 7, pp. 2335-2341.
    [Online] DOI: 10.1007/s00216-006-1106-x
  • Quetel, CR., Snell, JP., Aregbe, Y., Abranko, L., Jokai, Z., Brunori, C., Morabito, R., Hagan, W., Azemard, S., Wyse, E., Fajon, V., Horvat, M., Logar, M., Donard, OFX., Krupp, EM., Entwisle, J., Hearn, R., Schantz, M., Inagaki, K., Takatsu, A., Grinberg, P., Willlie, S., Dimock, B., Hintelmann, H., Zhu, J., Gonzalez, EB., Centineo, G., Alonso, JEG., Sanz-Medel, A. & Bjorn, E. (2005). 'Methylmercury in tuna: demonstrating measurement capabilities and evaluating comparability of results worldwide from the CCQM P-39 comparison'. Journal of Analytical Atomic Spectrometry, vol 20, no. 10, pp. 1058-1066.
    [Online] DOI: 10.1039/b505368d
  • Pavageau, MP., Morin, A., Seby, F., Guimon, C., Krupp, EM., Pecheyran, C., Poulleau, J. & Donard, OFX. (2004). 'Partitioning of metal species during an enriched fuel combustion experiment: Speciation in the gaseous and particulate phases'. Environmental Science & Technology, vol 38, no. 7, pp. 2252-2263.
    [Online] DOI: 10.1021/es034408i
  • Monperrus, M., Krupp, EM., Amouroux, D., Donard, OFX. & Martin-Doimeadios, RC. (2004). 'Potential and limits of speciated isotope-dilution analysis for metrology and assessing environmental reactivity'. Trends in Analytical Chemistry, vol 23, no. 3, pp. 261-272.
    [Online] DOI: 10.1016/S0165-9936(04)00313-9
  • Moldovan, M., Krupp, EM., Holliday, AE. & Donard, OFX. (2004). 'High resolution sector field ICP-MS and multicollector ICP-MS as tools for trace metal speciation in environmental studies: a review'. Journal of Analytical Atomic Spectrometry, vol 19, no. 7, pp. 815-822.
    [Online] DOI: 10.1039/b403128h
  • Martin-Doimeadios, RCR., Monperrus, M., Krupp, EM., Amouroux, D. & Donard, OFX. (2003). 'Using speciated isotope dilution with GC-inductively coupled plasma MS to determine and unravel the artificial formation of monomethylmercury in certified reference sediments'. Analytical Chemistry, vol 75, no. 13, pp. 3202-3211.
    [Online] DOI: 10.1021/ac026411a
  • Sturgeon, RE., Wahlen, R., Brandsch, T., Fairman, B., Wolf-Briche, C., Alonso, JIG., Gonzaalez, PR., Encinar, JR., Sanz-Medel, A., Inagaki, K., Takatsu, A., Lalere, B., Monperrus, M., Zuloaga, O., Krupp, EM., Amouroux, D., Donard, OFX., Schimmel, H., Sejeroe-Olsen, B., Konieczka, P., Schultze, P., Taylor, P., Hearn, R., Mackay, L., Myors, R., Win, T., Liebich, A., Philipp, R., Yang, L. & Willie, S. (2003). 'Determination of tributyltin in marine sediment: Comite Consultatif pour la Quantite de Matiere (CCQM) pilot study P-18 international intercomparison'. Analytical and Bioanalytical Chemistry, vol 376, no. 6, pp. 780-787.
    [Online] DOI: 10.1007/s00216-003-2016-9
  • Monperrus, M., Zuloaga, O., Krupp, EM., Amouroux, D., Wahlen, R., Fairman, B. & Donard, OFX. (2003). 'Rapid, accurate and precise determination of tributyltin in sediments and biological samples by species specific isotope dilution-microwave extraction-gas chromatography-ICP mass spectrometry'. Journal of Analytical Atomic Spectrometry, vol 18, no. 3, pp. 247-253.
    [Online] DOI: 10.1039/b203242m
  • Martin-Doimeadios, RCR., Stoichev, T., Krupp, EM., Amouroux, D., Holeman, M. & Donard, OFX. (2002). 'Micro-scale preparation and characterization of isotopically enriched monomethylmercury'. Applied Organometallic Chemistry, vol 16, no. 10, pp. 610-615.
    [Online] DOI: 10.1002/aoc.350
  • Martin-Doimeadios, RCR., Krupp, EM., Amouroux, D. & Donard, OFX. (2002). 'Application of isotopically labeled methylmercury for isotope dilution analysis of biological samples using gas chromatography/ICPMS'. Analytical Chemistry, vol 74, no. 11, pp. 2505-2512.
    [Online] DOI: 10.1021/ac011157s
  • Aguerre, S., Pecheyran, C., Lespes, G., Krupp, EM., Donard, OFX. & Potin-Gautier, M. (2001). 'Optimisation of the hyphenation between solid-phase microextraction, capillary gas chromatography and inductively coupled plasma atomic emission spectrometry for the routine speciation of organotin compounds in the environment'. Journal of Analytical Atomic Spectrometry, vol 16, no. 12, pp. 1429-1433.
  • Amouroux, D., Tessier, E., Krupp, EM., Caumette, P. & Donard, OFX. (2001). 'Interactions between selenium and sulfur biogeochemistry in the marine environment leading to bio-volatilization pathways'. Abstracts of Papers of the American Chemical Society, vol 221, pp. U448-U449.
  • Krupp, EM., Pecheyran, C., Pinaly, H., Motelica-Heino, M., Koller, D., Young, SMM., Brenner, IB. & Donard, OFX. (2001). 'Isotopic precision for a lead species (PbEt4) using capillary gas chromatography coupled to inductively coupled plasma-multicollector mass spectrometry'. Spectrochimica Acta. Part B: Atomic Spectroscopy, vol 56, no. 7, pp. 1233-1240.
  • Krupp, EM., Pecheyran, C., Meffan-Main, S. & Donard, OFX. (2001). 'Precise isotope-ratio measurements of lead species by capillary gas chromatography hyphenated to hexapole Multicollector ICP-MS'. Fresenius’ Journal of Analytical Chemistry, vol 370, no. 5, pp. 573-580.
  • Hirner, AV., Krupp, EM., Schulz, F., Koziol, M. & Hofmeister, W. (1998). 'Organometal(loid) species in geochemical exploration: preliminary qualitative results'. Journal of Geochemical Exploration, vol 64, no. 1-3, pp. 133-139.
  • Krupp, EM., Grumping, R., Furchtbar, URR. & Hirner, AV. (1996). 'Speciation of metals and metalloids in sediments with LTGC/ICP-MS'. Fresenius’ Journal of Analytical Chemistry, vol 354, no. 5-6, pp. 546-549.

Scientific Reviews

  • Feldmann, J. & Krupp, EM. (2011). 'Critical review or scientific opinion paper: Arsenosugars-a class of benign arsenic species or justification for developing partly speciated arsenic fractionation in foodstuffs?'. Analytical and Bioanalytical Chemistry, vol 399, no. 5, pp. 1735-1741.
    [Online] DOI: 10.1007/s00216-010-4303-6

Editorials

  • Feldmann, J. & Krupp, EM. (2012). 'Elemental imaging and speciation in plant science'. Analytical and Bioanalytical Chemistry, vol 402, no. 10, pp. 3261-3262.
    [Online] DOI: 10.1007/s00216-012-5758-4

Abstracts

  • Donard, OFX., Krupp, EM., Pecheyran, C., Amouroux, D. & Fitzgerald, WF. (2003). 'Fractionation of mercury at the molecular level in tuna and whale from world oceans: Potential and limits of this novel approach to assess global mercury cycling'. Geochimica et Cosmochimica Acta, vol 67, no. 18 Suppl. 1, pp. A81.

Contributions to Conferences

Abstracts

  • Mestrot, A., Plantevin, T., Hossain, M., Islam, MR., Roman-Ross, G., Krupp, EM., Feldmann, J. & Meharg, AA. (2010). 'Arsenic biovolatilization from soil: A global phenomenon?'. pp. A703.
  • Mestrot, A., Krupp, EM., Feldmann, J. & Meharg, AA. (2009). 'Biovolatilisation of arsenic [conference abstract]'. Goldschmidt Conference 2009, Davos, Switzerland, 21/06/09 - 26/06/09, pp. A875.

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